This book offers a comprehensive and cutting-edge overview of nanoionics, covering fundamental principles, experimental techniques, emerging trends, and advanced topics, making it a one-stop resource for both beginners and professionals in the field.
Table of ContentsPreface
1. Nanoionics for Energy Storage and Conversion: Materials and TechnologiesNawishta Jabeen, Adeela Naz, Imtiaz Ahmad and Ahmad Hussain
1.1 Introduction
1.2 Nanoionics for Energy Storage
1.2.1 Nanoionics for Batteries
1.2.2 Nanoionics for Supercapacitors
1.2.3 Nanoionics for Fuel Cell
1.3 Nanostructured Materials of Transport Behavior
1.3.1 Accumulating of Space Charges
1.3.2 Space Charges Depletion
1.4 Nanomaterials for Energy Storage Applications
1.4.1 Nanoionics Application and Technologies in Fuel Cells
1.4.2 Nanoionics Application and Technologies in Lithium Batteries
1.4.2.1 Nanocrystalline Electrodes
1.4.2.2 Shape of the Curve and Cell Voltage
1.4.2.3 Low Potential Extra Storage of Lithium
1.4.2.4 Interfacial Lithium Storage: Phenomenological Model
1.4.3 Nanoionics Application and Technologies in Supercapacitors
1.4.3.1 Novel Nanoionic Phenomena, Effects, and Physicochemical Nano Systems
1.4.3.2 Ionic Conductors Classification: Innovative Superionic Conductors
1.4.3.3 AdSIC/EC Heterojunctions for Ion-Electron Mechanisms
1.4.3.4 Creation of Nanoionic Supercapacitors: Models and Methods
1.4.3.5 AdSIC-Based Devices
1.4.3.6 Deep-Sub-Voltage Nanoelectronics as Impulse Storage Capacitors in
1.4.3.7 Micron Size Supercapacitors Based Advanced Superionic Conductors
1.4.4 Nanoionics Application and Technologies in Novel Memory Devices
1.4.4.1 Resistive-Switching Memories of Nanoionics
1.4.4.2 Memristors for Non-Volatile Memories (NVM)
1.4.4.3 Memristors for Artificial Synapses
1.4.4.4 Recognition of LTP and STP in Oxide Memristors
1.4.4.5 Realization of STDP in Oxide Memristors
1.5 Prospects and Outlook: Why Nanoionics?
1.5.1 Future of Nanoionic Devices
1.6 Conclusions
References
2. Fundamentals of Nanoionics and their ApplicationsMustafa Aamir Hussain, Shruti Mishra, Nisha V. Bora and Leena V. Bora
2.1 Introduction
2.2 Applications
2.2.1 Employment of Interface - Dominant Materials (IDMs) in Novel Solid State Power Devices
2.2.1.1 Micro Solid Oxide Fuel Cells (μSOFC)
2.2.1.2 Ion Gated Thermoelectrics
2.2.1.3 Solid Oxide Photoelectrochemical Cells (SOPECs)
2.2.2 Nanoarchitectonics for Atom-Based Devices
2.2.3 Biological Nanoionics
2.2.4 Artificial Nanoionics
2.2.4.1 Liquid Nanoionics
2.2.5 Utilization of Nanochannels for Electrochemical Energy Storage
2.2.5.1 Lithium-Ion Batteries (LIB)
2.2.5.2 Lithium Sulfur Batteries
2.2.5.3 Lithium Organic Batteries (LOB)
2.2.6 Nanocrystalline Structures
2.2.6.1 Sol-Gel (Chemical Deposition Method)
2.2.6.2 Microstructure Investigation
2.2.6.3 Storage of Hydrogen
2.3 Future Perspective
2.4 Conclusion
References
3. Nanomaterials for Nanoionics Applications: Synthesis, Characterization and Device IntegrationAmita, A.S. Mathur and B.P. Singh
3.1 Introduction
3.2 Synthesis of Nanomaterials
3.2.1 Chemical Route of Synthesis of Nanomaterials
3.2.2 Physical Route of Synthesis of Nanomaterials
3.2.3 Biological Route of Synthesis of Nanomaterials
3.3 Characterization of Nanomaterials
3.3.1 Surface Morphology, Surface Area, Size and Shape of Nanoparticles
3.3.2 Analysis of Elemental and Mineral Composition
3.3.3 Structures and Bonds in Nanoparticles
3.3.4 Magnetic Properties of Nanoparticles
3.4 Device Integration of Nanoionics
3.4.1 Resistive Switching Memories
3.4.2 Lithium Batteries
3.5 Summary and Future Prospects
References
4. Nano-Porous Silica in Devices and Ion-Based Systems - Unveiling the Design, Fabrication, and Diverse ApplicationsRupesh K. Tiwari and Rajendra K. Singh
4.1 Introduction
4.2 Methods Used for Synthesis of Nanoporous Silica
4.3 Applications of Nanoporous Silica in Various Fields
4.3.1 Biomedical
4.3.2 Water Decontamination
4.3.3 Energy
4.4 Conclusion
Acknowledgement
References
5. Bioinspired Nanoionics for Biomedical and Bioelectronic ApplicationsMasooma Siddiqui, Maroof Ali, Uzma, Azfar Jamal and Mohd Imran Ahamed
5.1 Introduction
5.2 Biomimetic Ion Transport Systems
5.2.1 Ion Channels
5.2.2 Ion Pumps
5.2.3 Ion Exchangers
5.2.4 Biomimetic Ion Transport Systems in Drug Delivery
5.2.5 Biomedical Applications
5.2.5.1 Drug Delivery
5.2.5.2 Bioimaging
5.2.5.3 Tissue Engineering
5.2.6 Bioelectronic Applications
5.2.6.1 Ion-Selective Sensors
5.2.6.2 Neuroprosthetics
5.2.6.3 Energy Storage
5.3 Biomimetic Materials in Bioinspired Nanoionics
5.3.1 Bioresponsive Polymers
5.3.2 Bioinspired Nanocomposites
5.3.3 Nanoparticle-Based Ion Carriers
5.4 Biomedical Breakthroughs
5.4.1 Organelle-Targeted Drug Delivery
5.4.2 Theranostics: Simultaneous Therapy and Imaging
5.4.3 Artificial Biomimetic Organs
5.5 Bioelectronic Innovations
5.5.1 Bioelectronic Skin
5.5.2 Ionic Circuitry
5.5.3 Bioelectronic Therapeutics
5.6 Biocompatibility and Safety
5.7 Ethical and Regulatory Consideration
5.8 Conclusion
References
6. Nanoionics in Biomedical Applications: Diagnostic and Therapeutic ApproachesTasnim Mahzabin Tanha, Md. Ahad Ali and Md. Abu Bin Hasan Susan
6.1 Introduction to Nanoionics
6.2 Types of Nanoionics
6.2.1 Biological Nanoionics
6.2.2 Artificial Nanoionics
6.2.3 Biological-Artificial Hybrid Nanoionics
6.3 General Applications of Nanoionics
6.4 Applications of Nanoionics in Diagnosis
6.5 Applications of Nanoionics in Therapeutics
6.5.1 Nanoionics in Cancer Therapy
6.5.2 Nanoionics as Antibiotics
6.6 Conclusions
References
7. Nanoionics in Electronics and Optoelectronics: Advances and ApplicationsMost. Israt Jahan, Md. Enamul Kabir, Md. Abu Bin Hasan Susan and Muhammed Shah Miran
7.1 Introduction
7.2 Development of Nanoionic Materials
7.2.1 Electronics
7.2.2 Optoelectronics
7.3 Application of Nanoionics in Electronics
7.3.1 Resistive Switching
7.3.2 Memristive Devices
7.3.2.1 Redox Reactions Initiated by the Migration of Cations
7.3.2.2 Redox Reactions Initiated by the Migration of Anions
7.3.3 Transistor
7.4 Application of Nanoionics in Optoelectronics
7.4.1 Light Emitting Diode
7.4.2 Solar Cell
7.4.3 Photo Assisted Switch
7.4.4 High-Performance Optical Sensors
7.5 Future Perspectives and Challenges
7.6 Conclusions
References
8. Challenges and Opportunities in Nanoionics: Towards Breakthrough ApplicationsSaranya J., Selvakumar V. S., Suganthi S., T. Helan Vidhya and Dinesh K.
8.1 Introduction
8.2 Mechanism Behind Nanoionics
8.3 Significance of Nanomaterials in Nanoionics
8.3.1 Metal Oxide Nanomaterials
8.3.2 Ceramic Nanomaterials
8.3.3 Polymeric Nanomaterials
8.3.4 Carbon-Based Nanomaterials
8.3.5 Two-Dimensional (2D) Materials
8.3.6 Hybrid Nanostructures
8.3.7 Nanocomposites
8.4 Energy Storage Applications
8.5 Emerging Electronics
8.5.1 Memory Devices
8.5.2 Sensors
8.5.3 Energy Harvesting Devices
8.6 Challenges in Nanoionics Technology
8.7 Sustainability and Ethical Considerations in Nanoionics
8.8 Cross-Disciplinary Opportunities
8.9 Educational Outreach and Knowledge Transfer
8.10 Significance of Nanoionics in Industrial Revolution
8.11 Innovation and Future Prospects
Conclusion
References
9. Nanoscale Modeling and Simulation in Nanoionics: Insights into Material Behavior and Device DesignM. Rizwan, A. Ayub, I-S. Ilyas, K. Zaman and G. Nabi
9.1 Introduction
9.2 Modeling and Simulation Methods in Nanoionics
9.2.1 Molecular Dynamic Simulations (MD)
9.2.2 Charge Transport Model (CTM) for Nanoionic Memristors
9.2.3 Linear Drift Memristor Model
9.2.4 SPICE Model for Memristors
9.2.5 Structure-Dynamic Approach (SDA)
9.2.6 Finite Element Method (FEM) Model
9.3 Nanoionic Memristors
9.3.1 Types of Memristors
9.4 Resistor-Switching Devices Design
9.4.1 A Cation-Based Resistive-Switching Effect
9.4.2 B Anion-Based Resistive-Switching Effect
9.4.3 Cation and Anion-Based Resistive-Switching Effect
9.5 Quantum-Point Contacts
9.6 Magnetic Nanostructures
9.7 Selector Devices
9.8 Future Perspective
References
10. Commercialization and Industrial Aspects of Nanoionics: Lab to MarketM. Rizwan, H. Hameed, A. Ayub, G. Nabi and M. Tanveer
10.1 Introduction
10.1.1 Importance in Emerging Technologies
10.1.1.1 Advancements in Energy Storage Applications
10.1.1.2 Next-Generation Electronics
10.1.1.3 Transformation in Sensor Technologies
10.2 Commercialization Challenges
10.2.1 Navigating Health and Environmental Concerns
10.2.2 Ensuring Safety in Nanoionic Applications
10.2.3 The Role of Public Awareness and Acceptance
10.2.4 Mitigating Risks Associated with Nanoproduct Exposure
10.3 Nano-Ionic Memory: Implications for the Economy
10.4 Future Prospects
10.5 Conclusion
References
11. Ion Migration and Defects in Nanostructures: Implications for Device Performance and ReliabilityM. Rizwan, M. Aqeel, I.-M. Arshad, A. Ayub and G. Nabi
11.1 Introduction
11.2 Ion Migration in Nanoionics
11.2.1 Types of Migration
11.2.1.1 Cation Migration
11.2.1.2 Anion Migration
11.3 Effect of Local Ion Migration on Device Performance
11.3.1 Modified Electrical Properties
11.3.2 Material Degradation
11.3.3 Memory Devices and Resistive Switching
11.3.4 Battery Performance
11.3.5 Corrosion and Chemical Reactions
11.3.6 Effect of Neighbourhood Ion Migration on Tool Overall Performance
11.4 Limitations of Ion Migration
11.5 Defects in Nanoionics
11.5.1 Point Defect Chemistry
11.5.2 Size Defects
11.5.3 Bulk Defects and Interfacial Thermodynamics
11.5.4 Chemical Flaws in Nanocrystalline Structures and Systems
11.6 Key Advances in Nanoionics and Improvements in Device Quality
11.6.1 Biological Nanoionics
11.7 Conclusion
References
12. Nanofluidics and Ion Transport at the Nanoscale: Manipulation and Sensing ApplicationsNadia Akram, Ameer Hamza, Muhammad Ibrahim, Muhammad Usman, Akbar Ali and Khalid Mahmood Zia
12.1 Introduction
12.2 Fundamentals of Nanofluidics
12.2.1 Nanoscale Fluid Behavior
12.2.1.1 Surface Effects
12.2.1.2 Viscosity Changes
12.2.1.3 Transport Phenomena
12.2.1.4 Electrokinetic Phenomena
12.2.2 Nanofluidic Devices
12.2.2.1 Nanochannels and Nanopores
12.2.2.2 Lab-on-a-Chip Devices
12.2.2.3 Fluid Transport in Nanoscale Conduits
12.2.2.4 Biological and Chemical Sensing
12.2.2.5 Fluidic Control and Manipulation
12.2.2.6 Energy Harvesting and Storage
12.2.2.7 Two-Dimensional Materials in Nanofluidics
12.2.3 Nanofluidic Devices Performance and Reliability
12.2.3.1 Conductance Measurements
12.2.3.2 Electrochemical Measurements
12.2.3.3 Scanning Electron Microscopy (SEM)
12.2.3.4 Atomic Force Microscopy (AFM)
12.2.3.5 Electron Microscopy
12.2.3.6 High-Resolution Imaging
12.2.3.7 Electrochemical Impedance Spectroscopy (EIS)
12.2.3.8 Capillary Filling
12.2.3.9 Tools for Microfabrication
12.2.3.10 Systematic Analysis
12.3 Advances in Nano Ionics and Improvement in Device Quality
12.3.1 Graphene-Based Energy Storage Devices
12.3.2 Nanostructured Metal-Based Electrodes
12.3.3 2D Nanosheets and MOF Nanosheets
12.4 Ion Transport Mechanisms
12.4.1 Electrophoresis
12.4.2 Electroosmosis
12.4.3 Ion Concentration Polarization (ICP)
12.4.4 Capillary Electrophoresis
12.4.5 Ion Selectivity
12.4.6 Coupling of Ion and Fluid Transport
12.5 Manipulation Techniques at the Nanoscale
12.5.1 External Fields and Nanofluidic Control
12.5.1.1 Electric Fields
12.5.1.2 Magnetic Fields
12.5.2 Microfluidic Integration
12.5.3 Hybrid Micro-Nanofluidic Systems
12.5.4 Synergy with Traditional Microfluidics
12.5.5 Sensing Applications
12.5.6 Chemical Sensing
12.5.6.1 Ion Sensing
12.5.6.2 Gas Sensing
12.5.7 Biosensing
12.5.7.1 Detection of Molecules
12.5.7.2 DNA Sequencing
12.5.8 Single-Molecule Sensing
12.5.8.1 Point-of-Care Diagnostics
12.5.8.2 Nano Biosensors: Point-of-Care Device
12.6 Emerging Trends and Challenges
12.6.1 Recent Advances in Nanofluidic Research
12.6.2 Current Challenges and Limitations
12.6.2.1 The Effects of Nanofluids on Reservoirs
12.6.2.2 The Nanofluids’ Economic Viability
12.7 Conclusion
References
13. Bioinspired Micro/NanorobotsYuchao Li, Tong He, Jiaqi Xu, Xixi Chen and Baojun Li
13.1 Introduction
13.2 Inspiration from Creatures of Nature
13.3 Actuation of Bioinspired Micro/Nanorobots
13.3.1 Magnetic Field-Propelled Micro/Nanorobots
13.3.1.1 Helical Magnetic Swimmers
13.3.1.2 Flexible Magnetic Swimmers
13.3.2 Ultrasonic Field-Propelled Micro/Nanorobots
13.3.3 Light-Propelled Micro/Nanorobots
13.3.3.1 Photocatalytic Propulsion and Collective Behaviors
13.3.3.2 Light-Driven Smart Soft Micro/Nanorobots
13.4 Biomedical Applications of Micro/Nanorobots
13.4.1 Sensing, Diagnosis and Isolation
13.4.2 Targeted Delivery and Photodynamic Therapy
13.5 Conclusion
Acknowledgments
References
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